Bachler of Science Syllabus Detail
Genius Mind Chemistry Classes Provide Quality Education For 12th UP BOARD & CBSE BOARD And Also Provide Preparation For Medical Or Engineering Entrance Examination for Chemistry .
B.SC III Year
Paper I CH-301 Inorganic Chemistry
I Hard and Soft Acids and Bases (HSAB)
Classification of acids and bases as hard and soft. Pearson's HSAB concept, acid-base strength and hardness and softness. Symbiosis, theoretical basis of hardness and softness, electronegativity and hardness and softness.
II Metal-ligand Bonding in Transition Metal Complexes
Limitations of valence bond theory, an elementary idea of crystal-field theory, crystal field splitting in octahedral, tetrahedral and square planar complexes, factors affecting the crystal-field parameters.
III Magnetic Properties of Transition Metal Complexes
Types of magnetic behaviour, methods of determining magnetic susceptibility, spin-only formula. L-S coupling, correlation of μs and μen values, orbital contribution to magnetic moments, application of magnetic moment data for 3d-metal complexes.
IV Electron Spectra of Transition Metal Complexes
Types of electronic transitions, selection rules for d-d transitions, spectroscopic ground states, spectrochemical series, Orgel-energy level diagram for d1 and d9 states, discussion of the electronic spectrum of [Ti(H2O)6]3+ complex ion.
V Thermodynamic and Kinetic Aspects of Metal Complexes
A brief outline of thermodynamic stability of metal complexes and factors affecting the stability, substitution reactions of square planar complexes.
VI Organometallic Chemistry
Definition, nomenclature and classification of organometallic compounds. Preparation, properties, bonding and applications of alkyls and aryls of Li, Al, Hg, Sn and Ti, a brief account of metal-ethylenic complexes and homogeneous hydrogenation, mononuclear carbonyls and the nature of bonding in metal carbonyls.
VII Bioinorganic Chemistry
Essential and trace elements in biological processes, metalloporphyrins with special reference to haemoglobin and myoglobin. Biological role of alkali and alkaline earth metai ions with special reference to Ca2+ Nitrogen fixation.
VIII Silicones and Phosphazenes
Silicones and phosphazenes as examples of inorganic polymers, nature of bonding in triphosphazenes.